Chemical classification
a chemical classification based on composition as ascertained by chemical analysis.
In 1903 four American petrologists, Cross, Iddings, Pirsson, and
Washington, (CIPW) advanced a classification which is in reality based
on chemical composition. Analyses are first calculated into a set of standard minerals
(the norm) under fixed rules which are based
on the known laws of mineral formation in magmas. Certain important
rock-forming minerals, the amphiboles, pyroxenes, and micas, are not
utilised in the norm, because of their complex chemical composition.
Their components are distributed between the norm minerals, which are based on
magmatic molecules of fixed composition. The norm is divided into a salic a and a Femic group, the most important constituents of
which are the following :-
Salic Minerals. Femic
Minerals.
Quartz Diopside
Orthoclase Hypersthene
Albite Olivine
Anorthite Acmite (Aegirine)
Leucite Magnetite
Nepheline Ilmenite
Corundum Haematite
Zircon Apatite
The conception of the norm is found to be of
the greatest value in the comparison of igneous rocks.
Another
quasi-chemical mode of classifying igneous rocks is by the use of the saturation
principle, as expounded by Shand and Holmes.
The minerals
which are capable of existing in igneous rocks in the presence of free
silica are said to be saturated, they are minerals of high silication.
On the other
hand, certain minerals of low silication, especially olivine
and the felspathoids minerals (including analcite), are very rarely found in
association with quartz, and may be termed unsaturated. These facts may form the basis of a classification as follows: -
I.
Oversaturated rocks, containing free silica of magmatic origin.
II. Saturated
rocks, containing only saturated minerals.
III. Undersaturated
rocks, containing unsaturated minerals.
Or
Shands and Holmes classified the
igneous rocks as
(i) Supersaturated rocks. Also known
as oversaturated
rocks. Here, the excess of silica crystallizes as
quartz.
(ii) Saturated rocks. They have just
sufficient silica to form the stable silicate minerals but no free
quartz.
(iii) Under-saturated rocks. They
contain insufficient silica and minerals like olivine, nepheline,
leucite etc. are therefore present.
Mineralogical Classification
In
order to classify igneous rocks for research or teaching purpose, it is
convenient to consider mineralogical differences between different rocks. It is
easier than chemical classification because minerals can be easily identified
with naked eyes or microscope and their relative amount can be conveniently
estimated with a fair amount of accuracy. This classification considers
minerals as either essential, accessory or secondary. The first two
are of igneous origin while the secondary minerals could be either of
metamorphic or sedimentary origin. The essential minerals are abundant and
therefore, are necessary to the diagnosis of the rock type.
Accessory
minerals on
the other hand, are those in small amounts, and whose presence is not mandatory
for the classification of that rock. For example, apatite and iron oxides in
igneous rocks. Igneous minerals are also Subdivided into felsic and mafic
types. The term felsic is derived from the word’s feldspar,
feldspathoid and silica. While 'mafic' has been coined from ferro-magnesian
(Fe-Mg) minerals. Few of these minerals are as follows:
Felsic
– Quartz, Feldspar, Feldspathoids
Mafic
– Mics, Pyroxenes, Amphiboles, Olivine, Iron Oxides
Felsic
minerals are
light in colour, low melting point, low specific gravity, comparatively, of
late crystallisation.
The
mafic
minerals are dark coloured, higher specific gravity, higher melting
point and are early crystallised minerals.
Classification on the basis of colour Index
The
colour of a rock has been quantified by a value known as the colour index,
which is simply the volume percentage of dark minerals.
|
Rock Division |
Colour Index |
Example |
1 |
Leucocratic (Light
colour mineral) |
1-30 |
Granite |
2 |
Mesocratic (Grey
colour minerals) |
31-60 |
Gabbro |
3 |
Melanocratic (Dark
colour minerals) |
61-100 |
Peridotite |
Terms
like leucocratic
and melanocratic
refer to light coloured and dark coloured minerals respectively.
Usually the felsic minerals; are leucocratic and the rocks containing
more of mafic minerals are melanocratic. The rocks which are
pitch dark in colour are termed, as ‘hypermelanocratic’ Mesocratic rocks
are intermediate in colour.
TABULAR CLASSIFICATION-Taking into consideration all the principles of classification
i.e. mineral composition, silica saturation or contains as well as depth of
formation. Tabular classification of rock is evolved as this classification is
set in a Tabular form it is term as tabular classification.
In this
classification the vertical divisions are made on the basis of three felsic
mineral groups which are Quartz, Feldspar & Feldspathoid. It
is well known that quartz do not occur along with feldspathoid and by taking
this into consideration five divisions are made which are characterised by mineral
association as follows –
I)
Quartz
II)
Quartz + Feldspar
III)
Feldspar
IV)
Feldspar + Feldspathoid
V)
Feldspathoid
Later on, to
these six subdivisions is added which is mafic mineral predominant & felsic
minerals are absent.
Division I & II belongs to oversaturated class of Shand’s
and Holm’s classification.
Division III belongs to Saturated class
While Division IV, V, VI belongs to undersaturated class of shands
& Holm’s classification.
Horizontally classification
is made into plutonic, hypabyssal and volcanic groups. In the plutonic group
a further subdivision is made according to whether the rocks consist predominately
of felsic minerals or of mafic minerals, or show equal proportion of felsic and
mafic minerals and the rocks are placed depending upon the percentage of felsic
and mafic minerals.
All though
this system of classification is easier but a complicated one, therefore it is
not considered as a perfect system. Further it is assuming that tabular
classification is simply a method to arrange & describe the common igneous
rock in simplest manner.
Mineralogical character of Acidic Igneous rock
In general,
the chemical composition of rock is expressed in terms of oxides like SiO2,
Al2O3, Fe2O3, FeO, MgO, CaO etc.
among these different oxides silicon dioxides (SiO2) is always predominant in
igneous rocks. As the Percentage of silica is responsible for the formation of
different minerals and their association. It is very useful for the
classification of Igneous rocks into Acid / acidic, basic, ultrabasic etc. The
mineralogical classification of acid igneous rocks are as follows.
· The silica content is more
than 66%
· These rocks are rich
in silica, alumina & Alkali but are poor in calcium, magnesium
& Iron
· Usually they are composed of quartz,
Feldspar (Alkali Feldspar) and Muscovite. Mica which represent the late
stage of crystallization of magma.
· Acid igneous rock are Leucocratic
i.e. light coloured because they are rich in plae coloured mineral.
· Mafic minerals occur only as
accessory minerals.
· They have free primary quartz
and are always devoid of unsaturated minerals like Olivine, Felspathoids etc,
·
E.g. Granite, Pegmatite,
Rhyolite
Mineralogical
character of Basic Igneous rock
·
The basic igneous rock has 45 – 55 % silica.
·
In this rock mafic (dark
colour) minerals occurs as an essential mineral.
·
Quartz and Olivine are
generally absent or one of them may occur in small quantity and feldspar are
always plagioclase type.
·
In basic igneous rock silica
and alkali are less while Calcium, Magnesium & Iron are more in composition
as compared to acidic rocks.
·
The basic igneous rocks are
typical in melanocratic i.e. dark colour (e.g. basalt & gabbro)
Mineralogical character of Ultrabasic Igneous rock.
·
In ultrabasic igneous rock
free quartz is always absent.
·
Undersaturated & mafic
minerals occurs as essential minerals.
·
The ultrabasic igneous rocks
are feldspar and quartz poor and mostly composed of olivine, pyroxene &
amphibole minerals, biotite, chromite and iron oxide occurs as accessory
minerals.
·
They are melanocratic (dark
coloured) and are usually formed as a different product of early formed
minerals like Olivine, Pyroxene & Calcium rick Plagioclase.
·
E.g. Dunite, Peridotite,
Pyroxinite
Mineralogical character of Alkali Igneous rock.
·
This group of igneous rocks is
characterised by the presence of higher ratios of alkali to silica.
·
This rock contains a large
range of mineral species.
·
These rocks are characterised
by the presence of Alkali feldspar. Feldspathoid & Na or K rick
Ferromagnesium minerals.
·
They are rich in Orthoclase or
sanidine or sodic plagioclase and few ferromagnesium minerals like pyroxene,
Amphibole, or biotite.
·
E.g. Alkali basalt, Trachyte,
Syenite
Characters of some common igneous rocks and their Indian
occurrences
1. Granite - In the Eastern-Ghats, Rajasthan,
in the Himalayan ranges, these rocks are in abundance. They mostly contain,
orthoclase, quartz, muscovite and small amounts of hornblende.
2. Basalt - As deccan traps, occur in
abundance in Gujarat, Madhya Pradesh, Maharashtra, A.P. etc. Their mineralogic contents
are usually plagioclase, augite sometimes a little olivine.
3. Pegmatites - In Bihar, Andhra Pradesh and
Rajasthan. Felspar, (Quartz and mica are the usual minerals.)
4. Lamprophyres - These are dyke-rocks and are
believed to have arisen from the same general body of magma. Mostly occur in
the coal-fields where they are more prominent. In case of mica lamprophyres—
biotite is the dominant mineral. In Hornblende Lamprophyres, hornblende is
dominant. In Augite lamprophyres augite is dominant. But their occurrence is
rare.
5. Anorthosite - In Eastern Ghats, they are
found, in Bankura of West Bengal, Sitapundi Complex of Tamilnadu, Banpur, Angul
of Orissa. Dominantly composed of labradorite feldspar.
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